117 Ts

Unknown / predicted

Overview

Tennessine is a synthetic element; it has symbol Ts and atomic number 117. It has the second-highest atomic number, the joint-highest atomic mass of all known elements, and is the penultimate element of the 7th period of the periodic table. It is named after the U.S. state or region of Tennessee where key research institutions involved in its discovery are located.
The discovery of tennessine was officially announced in Dubna, Russia, by a Russian–American collaboration in April 2010, which makes it the most recently discovered element. One of its daughter isotopes was created directly in 2011, partially confirming the experiment's results. The experiment was successfully repeated by the same collaboration in 2012 and by a joint German–American team in May 2014. In December 2015, the Joint Working Party of the International Union of Pure and Applied Chemistry (IUPAC) and the International Union of Pure and Applied Physics (IUPAP), which evaluates claims of discovery of new elements, recognized the element and assigned the priority to the Russian–American team. In June 2016, the IUPAC published a declaration stating that the discoverers had suggested the name tennessine, a name which was officially adopted in November 2016.
Tennessine may be located in the "island of stability", a concept that explains why some superheavy elements are more stable despite an overall trend of decreasing stability for elements beyond bismuth on the periodic table. …

History

In December 2004, the Joint Institute for Nuclear Research (JINR) team in Dubna, Moscow Oblast, Russia, proposed a joint experiment with the Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee, United States, to synthesize element 117 — so called for the 117 protons in its nucleus. Their proposal involved fusing a berkelium (element 97) target and a calcium (element 20) beam, conducted via bombardment of the berkelium target with calcium nuclei: this would complete a set of experiments done at the JINR on the fusion of actinide targets with a calcium-48 beam, which had thus far produced the new elements 113–116 and 118. ORNL—then the world's only producer of berkelium—could not then provide the element, as they had temporarily ceased production, and re-initiating it would be too costly. Plans to synthesize element 117 were suspended in favor of the confirmation of element 118, which had been produced earlier in 2002 by bombarding a californium target with calcium. The required berkelium-249 is a by-product in californium-252 production, and obtaining the required amount of berkelium was an even more difficult task than obtaining that of californium, as well as costly: It would cost around 3.5 million dollars, and the parties agreed to wait for a commercial order of californium production, from which berkelium could be extracted. …

Properties

Other than nuclear properties, no properties of tennessine or its compounds have been measured; this is due to its extremely limited and expensive production and the fact that it decays very quickly. Properties of tennessine remain unknown and only predictions are available.

The stability of nuclei quickly decreases with the increase in atomic number after curium, element 96, whose half-life is four orders of magnitude longer than that of any subsequent element. All isotopes with an atomic number above 101 undergo radioactive decay with half-lives of less than 30 hours. No elements with atomic numbers above 82 (after lead) have stable isotopes. This is because of the ever-increasing Coulomb repulsion of protons, so that the strong nuclear force cannot hold the nucleus together against spontaneous fission for long. Calculations suggest that in the absence of other stabilizing factors, elements with more than 104 protons should not exist. However, researchers in the 1960s suggested that the closed nuclear shells around 114 protons and 184 neutrons should counteract this instability, creating an "island of stability" where nuclides could have half-lives reaching thousands or millions of years. …

Isotopes

The stability of nuclei quickly decreases with the increase in atomic number after curium, element 96, whose half-life is four orders of magnitude longer than that of any subsequent element. All isotopes with an atomic number above 101 undergo radioactive decay with half-lives of less than 30 hours. No elements with atomic numbers above 82 (after lead) have stable isotopes. This is because of the ever-increasing Coulomb repulsion of protons, so that the strong nuclear force cannot hold the nucleus together against spontaneous fission for long. Calculations suggest that in the absence of other stabilizing factors, elements with more than 104 protons should not exist. However, researchers in the 1960s suggested that the closed nuclear shells around 114 protons and 184 neutrons should counteract this instability, creating an "island of stability" where nuclides could have half-lives reaching thousands or millions of years. While scientists have still not reached the island, the mere existence of the superheavy elements (including tennessine) confirms that this stabilizing effect is real, and in general the known superheavy nuclides become exponentially longer-lived as they approach the predicted location of the island. Tennessine is the second-heaviest element created so far, and all its known isotopes have half-lives of less than one second. …