Post-transition metal
Gallium is a chemical element; it has symbol Ga and atomic number 31. Discovered by the French chemist Paul-Émile Lecoq de Boisbaudran in Paris, France, 1875,
elemental gallium is a soft, silvery metal at standard temperature and pressure with a complex orthorhombic crystal structure. In its liquid state, it becomes silvery white. If enough force is applied, solid gallium may fracture conchoidally. Gallium does not occur as a free element in nature, but rather as gallium(III) compounds in trace amounts in zinc ores (such as sphalerite) and in bauxite.
The melting point of gallium, 29.7646 °C (85.5763 °F; 302.9146 K), is used as a temperature reference point. One of only four metal elements that is liquid at, or near, normal room temperature, gallium will melt in a person's hands at normal human body temperature of 37 °C (99 °F). Gallium alloys with low temperatures are used in thermometers as a non-toxic and environmentally friendly alternative to mercury, and can withstand higher temperatures than mercury. A melting point of −19 °C (−2 °F), well below the freezing point of water, is claimed for the alloy galinstan (62–95% gallium, 5–22% indium, and 0–16% tin by weight), but that may be the freezing point with the effect of supercooling.
Gallium is predominantly used in electronics. Gallium arsenide, the primary chemical compound of gallium in electronics, is used in microwave circuits, high-speed switching circuits, and infrared circuits. …
In 1871, the existence of gallium was first predicted by Russian chemist Dmitri Mendeleev, who named it "eka-aluminium" from its position in his periodic table. He also predicted several properties of eka-aluminium that correspond closely to the real properties of gallium, such as its density, melting point, oxide character, and bonding in chloride.
Mendeleev further predicted that eka-aluminium would be discovered by means of the spectroscope, and that metallic eka-aluminium would dissolve slowly in both acids and alkalis and would not react with air. He also predicted that M2O3 would dissolve in acids to give MX3 salts, that eka-aluminium salts would form basic salts, that eka-aluminium sulfate should form alums, and that anhydrous MCl3 should have a greater volatility than ZnCl2. All of these predictions were later proven accurate.
Gallium was discovered using spectroscopy by French chemist Paul-Émile Lecoq de Boisbaudran in 1875 from its characteristic spectrum (two violet lines) in a sample of sphalerite. Later that year, Lecoq obtained the free metal by electrolysis of the hydroxide in potassium hydroxide solution.
He named the element "gallia", from Latin Gallia meaning 'Gaul', a name for his native land of France. It was later claimed that, in a multilingual pun of a kind favoured by men of science in the 19th century, he had also named gallium after himself: Le coq is French for 'the rooster', and the Latin word for 'rooster' is gallus. …
Elemental gallium is not found in nature, but it is easily obtained by smelting. Very pure gallium is a silvery blue metal that fractures conchoidally like glass.
Gallium forms alloys with most metals. It readily diffuses into cracks or grain boundaries of some metals such as aluminium, aluminium–zinc alloys and steel, causing extreme loss of strength and ductility called liquid metal embrittlement.
Under normal conditions, gallium does not crystallize in any of the simple crystal structures. Instead, its stable phase (Ga-I) is a complex orthorhombic structure with eight atoms in the conventional unit cell. Within a unit cell, each atom has only one nearest neighbor (at a distance of 244 pm). The remaining six unit cell neighbors are spaced 27, 30 and 39 pm farther away, and they are grouped in pairs with the same distance. The bonding between the two nearest neighbors is covalent; hence Ga2 dimers are seen as the fundamental building blocks of the crystal. This explains the low melting point relative to the neighbor elements, aluminium and indium. This structure is strikingly similar to that of iodine and may form because of interactions between the single 4p electrons of gallium atoms, further away from the nucleus than the 4s electrons and the [Ar]3d10 core. This phenomenon recurs with mercury with its "pseudo-noble-gas" [Xe]4f145d106s2 electron configuration, which is liquid at room temperature. …
Gallium does not exist as a free element in the Earth's crust, and the few high-content minerals, such as gallite (CuGaS2), are too rare to serve as a primary source. The abundance in the Earth's crust is approximately 16.9 ppm. It is the 34th most abundant element in the crust. This is comparable to the crustal abundances of lead, cobalt, and niobium. Yet unlike these elements, gallium does not form its own ore deposits with concentrations of > 0.1 wt.% in ore. Rather it occurs at trace concentrations similar to the crustal value in zinc ores, and at somewhat higher values (~ 50 ppm) in aluminium ores, from both of which it is extracted as a by-product. This lack of independent deposits is due to gallium's geochemical behaviour, showing no strong enrichment in the processes relevant to the formation of most ore deposits.
The United States Geological Survey (USGS) estimates that more than 1 million tons of gallium is contained in known reserves of bauxite and zinc ores. Some coal flue dusts contain small quantities of gallium, typically less than 1% by weight. However, these amounts are not extractable without mining of the host materials (see below). Thus, the availability of gallium is fundamentally determined by the rate at which bauxite, zinc ores, and coal are extracted.
Semiconductor applications dominate the commercial demand for gallium, accounting for 98% of the total. The next major application is for gadolinium gallium garnets. As of 2022, 44% of world use went to light fixtures and 36% to integrated circuits, with smaller shares equal to ~7% going to photovoltaics and magnets each.
Extremely high-purity (>99.9999%) gallium is commercially available to serve the semiconductor industry. Gallium arsenide (GaAs) and gallium nitride (GaN) used in electronic components represented about 98% of the gallium consumption in the United States in 2007. About 66% of semiconductor gallium is used in the U.S. in integrated circuits (mostly gallium arsenide), such as the manufacture of ultra-high-speed logic chips and MESFETs for low-noise microwave preamplifiers in cell phones. About 20% of this gallium is used in optoelectronics.
Worldwide, gallium arsenide makes up 95% of the annual global gallium consumption. It amounted to $7.5 billion in 2016, with 53% originating from cell phones, 27% from wireless communications, and the rest from automotive, consumer, fiber-optic, and military applications. The recent increase in GaAs consumption is mostly related to the emergence of 3G and 4G smartphones, which employ up to 10 times the amount of GaAs in older models.
Gallium arsenide and gallium nitride can also be found in a variety of optoelectronic devices which had a market share of $15.3 billion in 2015 and $18.5 billion in 2016. …
Gallium has 30 known isotopes, ranging in mass number from 60 to 89. Only two isotopes are stable and occur naturally, gallium-69 and gallium-71. Gallium-69 is more abundant: it makes up about 60.1% of natural gallium, while gallium-71 makes up the remaining 39.9%. All the other isotopes are radioactive, with gallium-67 being the longest-lived (half-life 3.2617 days). Isotopes lighter than gallium-69 usually decay through beta plus decay (positron emission) or electron capture to isotopes of zinc, while isotopes heavier than gallium-71 decay through beta minus decay (electron emission), possibly with delayed neutron emission, to isotopes of germanium. Gallium-70 can decay both ways, to zinc-70 or to germanium-70.
Gallium-67 and gallium-68 (half-life 67.84 min) are both used for imaging in nuclear medicine (see gallium scan).
Metallic gallium is not toxic. However, several gallium compounds are toxic.
Gallium halide complexes can be toxic. The Ga3+ ion of soluble gallium salts tends to form the insoluble hydroxide when injected in large doses; precipitation of this hydroxide resulted in nephrotoxicity in animals. In lower doses, soluble gallium is tolerated well and does not accumulate as a poison, instead being excreted mostly through urine. Excretion of gallium occurs in two phases: the first phase has a biological half-life of 1 hour, while the second has a biological half-life of 25 hours.
Inhaled Ga2O3 particles are probably toxic.